首页 | 本学科首页   官方微博 | 高级检索  
     检索      

La在La:PWO闪烁晶体中的作用机制探讨
引用本文:张明荣,胡关钦.La在La:PWO闪烁晶体中的作用机制探讨[J].发光学报,1997,18(4):320-322.
作者姓名:张明荣  胡关钦
作者单位:中国科学院上海硅酸盐研究所, 上海 201800
摘    要:根据掺La的PWO晶体(LaPWO晶体)的透射光谱和发射光谱随La浓度的变化特性及其电子顺磁共振(EPR)谱,作者认为,掺La使晶体产生了新的以(LaPb)2/3(VPb)1/3WO4为主的缺陷,LaPWO晶体的透光性能的改善主要是由于Pb空位(VPb)"的增加.而发光性能的降低则主要是(LaPb)和(VPb)"的共同作用.

关 键 词:钨酸铅晶体  La掺杂  点缺陷  闪烁性能

MECHANISM OF THE EFFECT OF La DOPING ON PbWO4 SINGLE CRYSTAL
Zhang Mingrong,Hu Guanqin,Li Peijun,Xu Li,Yin Zhiwen.MECHANISM OF THE EFFECT OF La DOPING ON PbWO4 SINGLE CRYSTAL[J].Chinese Journal of Luminescence,1997,18(4):320-322.
Authors:Zhang Mingrong  Hu Guanqin  Li Peijun  Xu Li  Yin Zhiwen
Institution:Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800
Abstract:From the results of EPR measurement,i.e.no signal in PbWO4 crystals doped with Lathanum (La:PWO),a conclusion that no EPR center exists in La:PWO crystals was made.The role of La doping was thought as to increase the concentration of Pb2+ vacancy (VPb)" that could improve the optical transmittance of the crystals.And the degradation of luminescent intensities with increasing La concentration may be due to the nonradiative energy transfer of La3+ ions at Pb2+ sites and Pb2+ vacancy.
Keywords:PbWO4 crystal          La doping          point defect          scintillation properties
本文献已被 CNKI 维普 等数据库收录!
点击此处可从《发光学报》浏览原始摘要信息
点击此处可从《发光学报》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号