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Mechanism of reaction between cobalt(II) oxide and ammonium chloride
Authors:V. A. Borisov  A. N. D’yachenko  R. I. Kraidenko
Affiliation:1. Tomsk National Research Polytechnic University, Tomsk, Russia
Abstract:A reaction between cobalt oxide and ammonium chloride was studied. A possible mechanism of this reaction was determined by TGA and DSC. The reaction products were identified by IR spectroscopy, chemical and XRD analyses. A multistage mechanism was established for reaction between cobalt oxide and ammonium chloride. Cobalt chloride was determined to be the final product; the reaction occurs via the formation and decomposition of (NH4)3CoCl5, (NH4)2CoCl4, and NH4CoCl3.
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