| 配合物[Cu(CAM)(H2O)2]的水热合成与结构表征 |
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| 引用本文： | 高洪苓,崔建中.配合物[Cu(CAM)(H2O)2]的水热合成与结构表征[J].无机化学学报,2007,23(6):1072-1074. |
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| 作者姓名： | 高洪苓 崔建中 |
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| 作者单位： | 天津大学化学系,天津,300072 |
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| 基金项目： | 天津大学校科研和教改项目 |
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| 摘 要： | A copper(II) complex Cu(CAM)(H2O)2], (CAM=4-hydroxypyridine-2,6-dicarboxylic acid), has been hydr-othermally synthesized and characterized by elemental analysis, IR, and X-ray diffraction single crystal structure analysis. It belongs to triclinic system, with space group P1, a=0.783 3(3) nm, b=0.796 5(3) nm, c=0.798 6(3) nm, α=100.340(6)°, β=93.768(6)°, γ=109.348(5)°, V=0.458 3(3) nm3, Z=2. The copper(II) ion is 5-coordinated and exhi bits a distorted square pyramidal coordination environment. The two coordinated aqueous molecules and the oxygen atoms from the ligand generate the intermolecular hydrogen bonds, which result in the 2D supramolecular network. CCDC: 227156.
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| 关 键 词： | 4-羟基吡啶-2，6-二甲酸 铜配合物 晶体结构 |
| 文章编号： | 1001-4861（2007）06-1072-03 |
| 修稿时间： | 2006-12-142007-04-05 |
Hydrothermal Synthesis and Crystal Structures of Complex [Cu(CAM)(H2O)2] |
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| GAO Hong-Ling and CUI Jian-Zhong.Hydrothermal Synthesis and Crystal Structures of Complex [Cu(CAM)(H2O)2][J].Chinese Journal of Inorganic Chemistry,2007,23(6):1072-1074. |
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| Authors: | GAO Hong-Ling and CUI Jian-Zhong |
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| Institution: | Department of Chemistry, Tianjin University, Tianjin 300072 and Department of Chemistry, Tianjin University, Tianjin 300072 |
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| Abstract: | |
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| Keywords: | 4-hydroxypyridine-2 6-dicarboxylic acid copper(II) complex crystal structure |
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