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利用氟硅烷提高溶胶-凝胶SiO2增透膜的疏水性
引用本文:晏良宏,蒋晓东,江波,吕海宾,袁晓东. 利用氟硅烷提高溶胶-凝胶SiO2增透膜的疏水性[J]. 强激光与粒子束, 2007, 19(8): 1313-1316
作者姓名:晏良宏  蒋晓东  江波  吕海宾  袁晓东
作者单位:1.中国工程物理研究院 激光聚变研究中心, 四川 绵阳 621900; 2. 四川大学 化学学院, 成都 610064
基金项目:国家高技术研究发展计划(863计划)
摘    要: 以正硅酸乙酯为前驱体,氨水为催化剂,采用溶胶 凝胶法制备了二氧化硅增透膜;通过自组装技术,用氟硅烷对膜层进行表面修饰,制得了疏水增透膜,克服了常规增透膜亲水的缺点。采用红外光谱、分光光度计、扫描探针显微镜和静滴接触角测量仪等测试手段分析了薄膜的特性。结果表明:疏水增透膜的峰值透光率为99.7%,疏水角为110°;氟硅烷自组装改性不影响二氧化硅增透膜的光学性能。

关 键 词:溶胶-凝胶  二氧化硅  疏水增透膜  自组装  氟硅烷
文章编号:1001-4322(2007)08-1313-04
收稿时间:2007-01-26
修稿时间:2007-01-26

Improving hydrophobic property of sol-gel antiveflective silica coatings by FAS
YAN Liang-hong,JIANG Xiao-dong,JIANG Bo,L Hai-bin,YUAN Xiao-dong. Improving hydrophobic property of sol-gel antiveflective silica coatings by FAS[J]. High Power Laser and Particle Beams, 2007, 19(8): 1313-1316
Authors:YAN Liang-hong  JIANG Xiao-dong  JIANG Bo  L Hai-bin  YUAN Xiao-dong
Affiliation:1. Research Center of Laser Fusion, CAEP, P. O. Box 919-988-5, Mianyang 621900, China; 2. School of Chemistry, Sichuan University, Chengdu 610064, China
Abstract:Using TEOS as precursor, ammonia as catalyst, silica antireflective coating was prepared by sol-gel process. To obtain hydrophobic properties, the silica coatings were surface-modified with fluoroal kylsilane(FAS) by self-assembly technique. FTIR-spectroscopy, UV-vis spectroscopy, scanning probe microscopy and contact angle measurement were used to measure the properties of the silica coatings. The results show that the peak transmittance of the hydrophobic coating is 99.7%, and the water contact angle of the hydrophobic coating is 110°. The FAS surface modification does not influence the optical properties of the coating, but improve its hydrophobicity remarkably.
Keywords:Sol-gel  Silica  Hydrophobic antireflective coating  Self-assembly  Fluoroal kylsilae
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