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The effect of microwave annealing on the electrical characteristics of lanthanum doped bismuth titanate films obtained by the polymeric precursor method
Authors:AZ Simões  BD Stojanovic  JA Varela
Institution:a Chemistry Institute, UNESP, Paulista State University, C.P. 355, 14801-970 Araraquara, SP, Brazil
b Materials Science and Technology, UNESP, Paulista State University, C.P. 473, 17033-36, Bauru, SP, Brazil
Abstract:Lanthanum doped bismuth titanate thin films (Bi3.25La0.75Ti3O12 - BLT) were produced by the polymeric precursor method and crystallized in a domestic microwave oven and in conventional furnace. Using platinum coated silicon substrates configuration, ferroelectric properties of the films were determined with remanent polarization Pr and a coercive field Ec of 3.9 μC/cm2 and 70 kV/cm for the film annealed in the microwave oven and 20 μC/cm2 and 52 kV/cm for the film annealed in conventional furnace, respectively. The films annealed in conventional furnace exhibited excellent retention-free characteristics at low infant periods indicating that BLT thin films can be a promise material for use in non-volatile memories. On the other hand, the pinning of domains wall causes a strong decay at low infant periods for the films annealed in the microwave furnace which makes undesireable the application for future FeRAMS memories.
Keywords:68  55a  77  80Dj  81  20Ka
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