Fluid multiphase equilibria and critical phenomena in binary and ternary mixtures of carbon dioxide, certain n-alkanols and tetradecane |
| |
Authors: | C J Peters L J Florusse S Hhre J de Swaan Arons |
| |
Institution: | Delft University of Technology, Department of Chemical Engineering and Materials Science, Laboratory of Applied Thermodynamics and Phase Equilibria, Julianalaan 136, 2628 BL, Delft, The Netherlands |
| |
Abstract: | Experimental results of fluid multiphase equilibria occurring in ternary mixtures of near-critical carbon dioxide, certain n-alkanols and tetradecane are presented. The following n-alkanols were used in this investigation: decanol, octanol, heptanol, hexanol and pentanol. In the ternary systems with decanol, octanol or heptanol a closed loop liquid-vapor two-phase region in the three-phase surface liquid-liquid-vapor was found. As far as the ternary system with decanol is concerned, this phenomenon is in agreement with an earlier and unexpected finding of Patton et al. (1993). In addition, it was also found in this study that the phase diagrams of the ternary mixtures with hexanol or pentanol as the n-alkanol show further complications. |
| |
Keywords: | theory experiments molecular interaction data critical liquid-liquid-vapor equilibria carbon dioxide n-alkanes n-alkanols hydrogen bonding |
本文献已被 ScienceDirect 等数据库收录! |
|