| Synthesis and Crystal Structure of a Novel Bimetallic Porphyrin Complex Salt {[MnTPP(CH_3OH)_2]_3Fe(CN)_6}·13H_2O |
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| 引用本文： | 刘国旗,靳丽丽,景欢旺.Synthesis and Crystal Structure of a Novel Bimetallic Porphyrin Complex Salt {[MnTPP(CH_3OH)_2]_3Fe(CN)_6}·13H_2O[J].结构化学,2007,26(7):801-804. |
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| 作者姓名： | 刘国旗 靳丽丽 景欢旺 |
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| 作者单位： | College of Chemistry and Chemical Engineering Lanzhou University，College of Chemistry and Chemical Engineering Lanzhou University，College of Chemistry and Chemical Engineering Lanzhou University，Lanzhou 730000 China，Lanzhou 730000 China，Lanzhou 730000 China |
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| 基金项目： | the Natural Science Foundation of Gansu Province (3ZS041-A25-008) |
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| 摘 要： | A novel bimetallic porphyrin complex salt, {MnTPP(CH3OH)2]3Fe(CN)6}13H2O (TPP = tetraphenylporphyrin), has been synthesized and structurally characterized by X-ray diffraction analysis. The crystal is of trigonal, space group R-3 with a = b = 31.0618(10), c = 11.8366(8) A, Z = 3, V = 9890.3(8) A3, C144H134FeMn3N18O19, Mr = 2641.36, Dc = 1.330 g/cm3, μ(MoΚα) = 0.463 mm-1, F(000) = 4131, R = 0.0525 and wR = 0.1382 for 3045 observed reflections (I > 2σ(I)). The title complex is composed of one Fe(CN)6]3- anion, three MnTPP(CH3OH)2]+ cations and thirteen water molecules, which are connected by multiform hydrogen bonds leading to a 3D supramolecular network structure.
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Synthesis and Crystal Structure of a Novel Bimetallic Porphyrin Complex Salt {[MnTPP(CH_3OH)_2]_3Fe(CN)_6}·13H_2O |
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| LIU Guo-Qi,JIN Li-Li,JING Huan-Wang,.Synthesis and Crystal Structure of a Novel Bimetallic Porphyrin Complex Salt {[MnTPP(CH_3OH)_2]_3Fe(CN)_6}·13H_2O[J].Chinese Journal of Structural Chemistry,2007,26(7):801-804. |
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| Authors: | LIU Guo-Qi JIN Li-Li JING Huan-Wang |
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| Abstract: | A novel bimetallic porphyrin complex salt, {MnTPP(CH3OH)2]3Fe(CN)6}13H2O (TPP = tetraphenylporphyrin), has been synthesized and structurally characterized by X-ray diffraction analysis. The crystal is of trigonal, space group R-3 with a = b = 31.0618(10), c = 11.8366(8) A, Z = 3, V = 9890.3(8) A3, C144H134FeMn3N18O19, Mr = 2641.36, Dc = 1.330 g/cm3, μ(MoΚα) = 0.463 mm-1, F(000) = 4131, R = 0.0525 and wR = 0.1382 for 3045 observed reflections (I > 2σ(I)). The title complex is composed of one Fe(CN)6]3- anion, three MnTPP(CH3OH)2]+ cations and thirteen water molecules, which are connected by multiform hydrogen bonds leading to a 3D supramolecular network structure. |
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| Keywords: | supramolecular network structure crystal structure hydrogen bond porphyrin potassium ferricyanide |
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