| 四苯基卟啉的微波合成 |
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| 引用本文： | 陈年友,赵胜芳,廖学红,舒峰. 四苯基卟啉的微波合成[J]. 武汉大学学报(理学版), 2004, 50(2): 169-172 |
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| 作者姓名： | 陈年友 赵胜芳 廖学红 舒峰 |
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| 作者单位： | 黄冈师范学院,化学系,湖北,黄冈,438000 |
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| 基金项目： | 湖北省教育厅重点科研项目基金资助(1999A083,2002A04002) |
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| 摘 要： | 采用微波辐射的方法合成四苯基卟啉。分析和讨论了溶剂、催化剂、微波辐射时间及微波输出功率等因素对合成产率的影响．结果表明：在溶剂为硝基苯、催化剂为氯乙酸、微波功率为195W、反应时间为6min的条件下合成四苯基卟啉，最高产率可达35．94％，优于文献结果．
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| 关 键 词： | 四苯基卟啉 微波合成 反应条件 合成产率 |
| 文章编号： | 1671-8836(2004)02-0169-04 |
| 修稿时间： | 2003-09-04 |
The Microwave Synthesis of Tetraphenyl-Porphyrin |
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| CHEN Nian-you,ZHAO Sheng-fang,LIAO Xue-hong,SHU Feng. The Microwave Synthesis of Tetraphenyl-Porphyrin[J]. JOurnal of Wuhan University:Natural Science Edition, 2004, 50(2): 169-172 |
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| Authors: | CHEN Nian-you ZHAO Sheng-fang LIAO Xue-hong SHU Feng |
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| Abstract: | Tetraphenyl-porphyrin was synthesized with microwave radiant method. The influence of solvent, catalyst, reactional period, reactional concentration and microwave radiant power in TPP synthesis on the yield of product has been analyzed and discussed. The experimental results show that the yield of tetraphenylporphyin may reach as high 35.94% under the condition of the uses of nitrobenzene as solvent, chloroacetic acid as catalyst and 195 W microwave intermittent radiation for 6 min. |
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| Keywords: | tetraphenyl-porphyrin microwave synthesis reactional condition |
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