3-Hydroxy-2-(2-thienyl)-4H-chromen-4-one as a new reagent for the extraction and trace determination of molybdenum(VI) |
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Authors: | Rameshwar and J R Mehta |
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Institution: | (1) Department of Chemistry, Kurukshetra University, 132119 Kurukshetra, India |
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Abstract: | A simple, sensitive and selective method for the extraction and trace determination of molybdenum(VI) has been developed; it is based on its reaction with 3-hydroxy-2-(2-thienyl)-4H-chromen-4-one (HTC) in sulphuric acid medium. The 1:2 Mo (VI)-HTC yellow complex is quantitatively extractable into chloroform ( max 420 nm) and is stable for more than 4 h. The procedure eliminates the interference of a large number of metal ions and complexing agents. Beer's law is obeyed in the range of 0–2.85 g Mo/mL with a molar absorptivity, Sandell's sensitivity and standard deviation of 5.28×104 L mol–1 cm–1, 0.0018 g Mo/cm2 and ±0.0054, respectively. The method has successfully been used for the spectrophotometric determination of molybdenum in steel samples. |
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