Synthesis and spectral properties of the Co2+ and Co3+ complexes with octaaryltetraazaporphyrins |
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Authors: | N. V. Chizhova O. G. Khelevina R. S. Kumeev B. D. Berezin N. Zh. Mamardashvili |
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Abstract: | Complexes Co2+ and Co3+ with octaphenyltetraazaporphyrin, octa(4-bromphenyl)tetraazaporphyrin and octa(4-nitrophenyl)tetraazaporphyrin were obtained and identified. The influence of the composition of reaction medium on the oxidation processes of the complexes Co2+ → Co3+ in DMF was revealed and the optimum conditions of formation of the corresponding compounds were determined. |
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