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Synthesis and spectral properties of the Co2+ and Co3+ complexes with octaaryltetraazaporphyrins
Authors:N. V. Chizhova   O. G. Khelevina   R. S. Kumeev   B. D. Berezin  N. Zh. Mamardashvili
Abstract:Complexes Co2+ and Co3+ with octaphenyltetraazaporphyrin, octa(4-bromphenyl)tetraazaporphyrin and octa(4-nitrophenyl)tetraazaporphyrin were obtained and identified. The influence of the composition of reaction medium on the oxidation processes of the complexes Co2+ → Co3+ in DMF was revealed and the optimum conditions of formation of the corresponding compounds were determined.
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