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Synthesis of 4,5‐Dihydrofuran‐3‐carbonitrile Derivatives with Electron‐Rich Alkenes in the Presence of Manganese(III) Acetate
Authors:Mehmet Yllmaz  E. Vildan Burgaz  Mehtap Yakut  Emre Biçer
Affiliation:1. Department of Chemistry, Faculty of Arts and Sciences, Kocaeli University, 41380, Umuttepe/Kocaeli, Turkey, Tel: +902623032058;2. Fax: +902623032003;3. Department of Chemistry, Faculty of Science, Ankara University, 06100, Tandogan/Ankara, Turkey;4. TUBITAK Marmara Research Center, Energy Institute, 41470, Gebze/Kocaeli, Turkey, Tel: +902626773459;5. Fax: +902626412309
Abstract:Radical cyclization reactions mediated by manganese(III) acetate were carried out with ν‐excessive alkenes ( 2a‐d ) and 3‐oxopropanenitriles ( 1a‐f ) resulting in the formation of 3‐cyano‐4,5‐dihydrofuran derivatives in poor to high yields. A mechanism was proposed for the cyclization reaction. The significance of the study is the formation of the 3‐cyano‐4,5‐dihydrofuran derivatives resembling terfuran, 2‐(2‐thienyl)furan and 2‐(2‐benzofuryl)furyl compounds having the fluorescent properties due to a conjugated ν‐electron system particularly containing the cyano moeity.
Keywords:Manganese(III)  Radical cyclization  3‐Cyano‐4,5‐dihydrofuran  3‐Oxopropanenitrile.
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