Synthesis and Micellar Behaviors of an Anionic Polymerizable Surfactant |
| |
| Authors: | Lihua Ma Yongjun Guo Rusheng Feng Panpan Xiang Chunhui Li |
| |
| Affiliation: | School of Chemistry and Chemical Engineering Department, Southwest Petroleum University, Chengdu, 610500, China |
| |
| Abstract: | A novel anionic polymerizable surfactant sodium (5‐acryloyl‐2‐(dodecyloxy)phenyl) methane sulfonate has been synthesized from phenol, acrylic acid and bromododecane by esterification, Frise rearrangement, sulfomethylation reaction and Williamson etherification. The parameters of the micellar behaviors are as follows: The CMC was 150 ppm at 40 °C; The surface absorption amounts Γm was 3.208 × 10?6 mol m?2; The molecular areas Am was 0.550 × 10?18m2 at the interface of air‐water respectively; The aggregation number (Nagg) at C = CMC of this surfactant was 12. |
| |
| Keywords: | Synthesis Polymerizable surfactant |
|
|
