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Water‐Soluble and Recyclable Cyclopalladated Ferrocenylimine for Suzuki Coupling Reaction
Authors:Yang Li  Zhihua Fu  Lu Rao  Li Wang  Rui Li  Tiesheng Li  Yangjie Wu
Institution:The College of Chemistry and Molecular Engineering, The Key Lab of Chemical Biology and Organic Chemistry of Henan Province, The Key Lab of Advanced Nano‐information Materials of Zhengzhou, Zhengzhou University, Kexuedadao 100, Zhengzhou 450001, P. R. China
Abstract:A series of new water‐soluble cyclopalladated ferrocenylimines were designed and prepared. They were efficient catalyst for Suzuki coupling reactions of aryl bromides and phenylboronic acid in neat water under ambient atmosphere. Among of these catalysts, the catalyst ( C2D ) could be reused for 6 times for the Suzuki coupling reaction of 4‐bromotoluene with phenylboronic acid in EtOH/H2O under ambient atmosphere, in which no significant loss activity of C2D was observed.
Keywords:Suzuki reaction  Water‐soluble catalyst  Aqueous media  Recycle
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