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Thermodynamics of curved boundary layers
Authors:M J Mandell  H Reiss
Institution:1. Department of Chemistry, University of California, Los Angeles, California
Abstract:A thermodynamic treatment of curved boundary layers is given which closely parallels the conventional theory of curved interfacial layers. The boundary analogs to the Gibbs adsorption isotherm and the Gibbs-Tolman-Koenig-Buff equation are derived.
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