Thermodynamics of curved boundary layers |
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Authors: | M J Mandell H Reiss |
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Institution: | 1. Department of Chemistry, University of California, Los Angeles, California
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Abstract: | A thermodynamic treatment of curved boundary layers is given which closely parallels the conventional theory of curved interfacial layers. The boundary analogs to the Gibbs adsorption isotherm and the Gibbs-Tolman-Koenig-Buff equation are derived. |
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