On the Hellmann–Feynman theorem and the corrections to the energy in the Rayleigh–Schrödinger perturbation theory |
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Authors: | Rafael Almeida Helena Diez y Riega Daniel A Morales |
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Institution: | (1) Departamento de Química, Universidad de Los Andes, La Hechicera, Merida, Edo, Merida, 5101, Venezuela |
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Abstract: | In this work we present an alternative method, based on the Hellmann–Feynman theorem, to generate energy corrections within the standard Rayleigh–Schrödinger perturbation theory. As a result, compact expressions for the corrections to the energy at different orders are obtained. We also review a method that allows us to calculate the corrections to the wave function needed in the energy calculations. Finally, our results are compared with those obtained by other authors by a different technique. |
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Keywords: | Hellmann– Feynman theorem perturbation theory |
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