Empty electronic states in the sodium tungsten bronzes: a study by inverse photoemission spectroscopy |
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Authors: | P.M.G. Allen P.J. Dobson R.G. Egdell |
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Affiliation: | Department of Physics, Imperial College, London SW7 2AZ, UK;Department of Chemistry, Imperial College, London SW7 2AZ, UK |
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Abstract: | Empty electronic states in the sodium tungsten bronze have been studied by inverse photoemission spectroscopy using a novel narrow-bandpass photon detector. The empty density of states in the t2g(W:5d) band peaks about 3 eV above the Fermi energy, implying an overall t2g bandwidth greater than found in recent bandstructure calculations. |
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