Electronic structure of the organic conductors based on BMDT-TTF (BIS(methylenedithio)tetrathiafulvalene) |
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| Authors: | Reizo Kato Hayao Kobayashi Takehiko Mori Akiko Kobayashi Yukiyoshi Sasaki |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science, Toho University, Funabashi, Chiba 274, Japan;2. Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo 113, Japan |
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| Abstract: | In the crystals of the cation radical salts based on the organic donor BMDT-TTF, the charge separation is observed. This comes from (1) nonequivalency of the site potential and (2) the long range electron-electron interaction, which are related to the two-dimensional nature of the molecular arrangement. The effects of the charge separation on the elctronic structure are discussed. |
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