Total synthesis of (-)-dysiherbaine |
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| Authors: | Celindro Nelma Carurucan Kim Tae Woo Kang Sung Ho |
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| Institution: | MIRC, Dept. of Chemistry, KAIST, Daejeon 305-701, Korea. |
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| Abstract: | The enantioselective synthesis of (-)-dysiherbaine (1) has been established with efficiency via a unique synthetic strategy involving the desymmetrization of 2-substituted glycerol to install a quaternary chiral carbon, which induces further stereochemistry in the bicyclic perhydrofuropyran through mercuriocyclization and epoxidation. |
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