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Colloidal glass transition observed in confinement
Authors:Nugent Carolyn R  Edmond Kazem V  Patel Hetal N  Weeks Eric R
Affiliation:Physics Department, Emory University, Atlanta, Georgia 30322, USA.
Abstract:We study a colloidal suspension confined between two quasiparallel walls as a model system for glass transitions in confined geometries. The suspension is a mixture of two particle sizes to prevent wall-induced crystallization. We use confocal microscopy to directly observe the motion of colloidal particles. This motion is slower in confinement, thus producing glassy behavior in a sample which is a liquid in an unconfined geometry. For higher volume fraction samples (closer to the glass transition), the onset of confinement effects occurs at larger length scales.
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