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A Robust Thermal Modulator for Comprehensive Two-Dimensional Gas Chromatography
Authors:John B. Phillips  Richard B. Gaines  Jan Blomberg  Frans W. M. van der Wielen  Jean-Marie Dimandja  Vaughn Green  James Granger  Don Patterson  Laell Racovalis  Henk-Jan de Geus  Jacob de Boer  Peter Haglund  John Lipsky  Veena Sinha  Edward B. Ledford
Abstract:In comprehensive two-dimensional gas chromatography (GC×GC), two capillary columns are connected in series through an interface known as a “thermal modulator”. This device transforms effluent from the first capillary column into a series of sharp injection-like chemical pulses suitable for high-speed chromatography on the second column. Dramatic increases in the resolving power, sensitivity, and speed of the gas chromatograph result. This paper describes the development of a robust and reliable thermal modulator for GC×GC.
Keywords:Multidimensional Gas Chromatography  orthogonal separations  GC×  GC  comprehensive two-dimensional chromatography  characterization of gasoline
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