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A Stable Calcium Alumanyl |
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| Authors: | Ryan J. Schwamm Martyn P. Coles Michael S. Hill Mary F. Mahon Claire L. McMullin Nasir A. Rajabi Andrew S. S. Wilson |
| Abstract: | A seven‐membered N,N′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg?Al and Ca?Al bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity. |
| Keywords: | alumanyl calcium density functional theory magnesium potassium |