| 甲基丙烯酸甲酯高转化聚合模拟动力学研究 |
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| 引用本文： | 朱鹏伟,常棉.甲基丙烯酸甲酯高转化聚合模拟动力学研究[J].高分子学报,1989,0(4):481-483. |
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| 作者姓名： | 朱鹏伟 常棉 |
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| 作者单位： | 福建师范大学高分子研究所 福州
(朱鹏伟)，大连轻工业学院应用化学系 大连(常棉) |
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| 摘 要： | <正> 聚合体系在高转化阶段,其动力学用常规方法难以解决,为了在实际生产中控制聚合反应,人们对聚合体系的高转化动力学进行了研究,但与实验相比都存在较大的偏。本文则用模拟函数方法,重新处理了这一问题,并根据实验散点图,拟合本实验条件下甲基丙烯酸甲酯本体聚合高转化阶段的动力学模型比前人更能精确地反映了实验事实,并且计算简便直观,无需其它动力学参数,从而为生产的自动控制提供了理论依据。 实验
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| 关 键 词： | 模拟 甲基丙烯酸甲酯 动力学 高转化率 |
| 收稿时间： | 1988-03-27 |
STUDY ON SIMULATION KINETICS OF POLYMERIZATION OF METHYL METHACRYLATE AT HIGH CONVERSION |
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| ZHU Pen-wei,CHANG Mian.STUDY ON SIMULATION KINETICS OF POLYMERIZATION OF METHYL METHACRYLATE AT HIGH CONVERSION[J].Acta Polymerica Sinica,1989,0(4):481-483. |
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| Authors: | ZHU Pen-wei CHANG Mian |
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| Institution: | Fujian Teachers University; Fuzhou; Dalian Institute of Light Industry; Dalian |
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| Abstract: | The kinetic character of polymerization of methyl methacrylate at high conversion was studied by means of simulation method of an approximate curver The corresponding kinetic equations were obtained, which Were simple and clear. The models were in better agreement with experimental results. |
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| Keywords: | Simulation Methyl methacrylate Kinetics High conversion |
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