Verfeinerung der Kristallstruktur des Dicaesium-Tetraazido-Zinkates Cs2Zn(N3)4 und die Kristallstrukturen komplexer Zinkazide |
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| Authors: | Franz A. Mautner Harald Krischner |
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| Affiliation: | (1) Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, A-8010 Graz, Austria;(2) Laboratoire de Cristallographie, Université de Geneve, CH-1211 Geneva, Switzerland |
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| Abstract: | Summary The crystal structure of dicesium-tetraazido-zincate, Cs2Zn(N3)4, has been refined from single crystal X-ray-diffractometer data. The previously reported orthorhombic structure, consisting of isolated Zn(N3)4-tetrahedra was confirmed and improved lattice parameters and atomic distances were determined. The azide groups are asymmetric and the coordination of central nitrogen atoms to cesium was observed. A table of structure data and mean atomic distances for fourteen zinc-azide compounds is added and the structures are discussed.Herrn Prof. Dr. Karl Torkar zum 70. Geburtstag gewidmet |
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| Keywords: | Azide Cesium Crystal structure Zinc |
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