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Electrochemical approaches for better understanding of atom transfer radical polymerization |
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| Authors: | Abdirisak A Isse Francesca Lorandi Armando Gennaro |
| Institution: | 1. Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131, Padova, Italy;2. Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, USA |
| Abstract: | Electrochemistry strongly contributed to deepen the understanding and predictability of atom transfer radical polymerization (ATRP) outcomes. Several electrochemical tools have been used to determine thermodynamic and kinetic parameters that are hardly accessible by other techniques. The electrochemical methods presented in this brief review were applied to systems with extremely different ATRP reactivity, providing a rational database of primary reference for further developments of ATRP. |
| Keywords: | Atom transfer radical polymerization Copper catalysis Homogeneous redox catalysis Inner sphere electron transfer Organocopper complexes |
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