Property and structure of various platinum catalysts for low-temperature carbon monoxide oxidations |
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Authors: | S Dey GC Dhal |
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Institution: | Department of Civil Engineering, IIT (BHU), Varanasi, India |
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Abstract: | The oxidation of carbon monoxide (CO) has received more attention in the last two to three decades owing to its importance in different fields. To control this CO pollution, catalytic converters have been investigated. Different types of catalysts have been used in a catalytic converter for CO emission control purposes. Platinum (Pt)-based noble metal catalysts show great potential for CO oxidation in catalytic converters with high thermal stability and tailoring flexibility. Pt metal catalysts modified with promoters such as alkali metals and reducible metal oxides have received great attention for their superior catalytic activities in CO oxidation. Temperature, close environment of the catalyst, and chemical composition in the surface layer of the catalyst have a huge effect on the active phase dispersion and O2 adsorption capacity of the Pt metal catalysts. The main difference in activities of Pt metal catalyst for CO oxidation in O2 or H2 atmosphere has found. The addition of supports in Pt metal catalysts has improved their performances and reduced their cost. These improvement strongly depends on the surface structure, morphology, number of active sites, and various Pt-O interactions. Many research articles have already been published in CO oxidation over Pt metal catalysts, but no review article dedicated to CO oxidation is available in the literature. |
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Keywords: | Carbon monoxide Platinum metal Chemisorptions Mechanism and applications |
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