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Efficient barrier properties of mechanically enhanced agro-extracted cellulosic biocomposites
Authors:U Qasim  R Fatima  M Usman
Institution:1. Department of Chemical Engineering, COMSATS University Islamabad, Lahore, 55150, Pakistan;2. Department of Chemistry, New Mexico Highlands University, Las Vegas, NM, 87701, USA
Abstract:The objective of this work was to prepare the mechanically stable hydrophobic biocomposites by incorporating the cellulose fibers into the polymer matrices for their applications in biomedical and food packaging. Herein, two different types of biocomposites were prepared by mixing polylactic acid (PLA) and polyhydroxybutyrate (PHB) with the agro-extracted cellulose, separately at 170 °C. The influence of the cellulose fibers on the thermal, mechanical, and barrier properties of polymer matrices (PLA and PHB) was observed. With an increase in the cellulose content in PLA and PHB, the tensile strength of the biocomposite materials significantly improved with the enhancement of 24.45% and 32.08%, respectively, compared with the pure PLA and PHB. Furthermore, a decrease of 74.16% and 73.49% in the water vapor transmission rate and oxygen transmission rate, respectively, was observed for cellulose/PHB biocomposites. This study highlights that adding cellulose fibers significantly improves the mechanical and the barrier properties of PLA and PHB, suggesting their biocomposites for use in biodegradable polymer industries.
Keywords:Wheat straw  Cellulose  Biodegradable polymers  Thermal properties  Mechanical properties
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