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| 萘酞菁硅配合物的合成及激发态性质研究 | |
| 引用本文： | 牛晓宇,林芬,吴谊群,陈耐生,黄金陵.萘酞菁硅配合物的合成及激发态性质研究[J].无机化学学报,2005,21(10):1450-1454. |
| 作者姓名： | 牛晓宇 林芬 吴谊群 陈耐生 黄金陵 |
| 作者单位： | 1. 福州大学功能材料研究所,福州,350002;黑龙江大学化学化工学院,哈尔滨,150080 2. 福州大学测试中心,福州,350002 3. 黑龙江大学化学化工学院,哈尔滨,150080;中国科学院上海光学精密机械研究所,上海,201800 4. 福州大学功能材料研究所,福州,350002 |
| 基金项目： | 国家自然科学基金(No.20141001)，黑龙江省自然科学基金(No.B01-07)资助项目 |
| 摘 要： | 本文合成了3种轴向配位的萘酞菁硅配合物(NcSiR2，R=Cl、OH、OCH3)，研究了3种萘酞菁配合物激发态性质，研究结果表明，随着轴向取代基推电子能力的逐渐增强，激发单线态寿命和激发三线态寿命逐渐缩短，产生单线态氧的能力逐渐下降。 |
| 关 键 词： | 硅萘酞菁配合物 激发单线态和三线态寿命 单线态氧 |
| 文章编号： | 1001-4861(2005)10-1450-05 |
| 收稿时间： | 2005-02-22 |
| 修稿时间： | 2005-06-29 |
Synthesis and Excitation Properties of Axially Substituted Silicon Naphthalocyanine (NcSiR2, R=Cl, OH, OCH3) |
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| NIU Xiao-Yu,LIN Fen,WU Yi-Qun,CHEN Nai-Sheng and HUANG Jin-Ling.Synthesis and Excitation Properties of Axially Substituted Silicon Naphthalocyanine (NcSiR2, R=Cl, OH, OCH3)[J].Chinese Journal of Inorganic Chemistry,2005,21(10):1450-1454. | |
| Authors: | NIU Xiao-Yu LIN Fen WU Yi-Qun CHEN Nai-Sheng and HUANG Jin-Ling |
| Institution: | Institute of Functional Materials, Fuzhou University, Fuzhou 350002;College of Chemistry and Chemical Engineering, Heilongjiang University, Harbin 150080,Center of Analysis and Mesurement, Fuzhou University, Fuzhou 350002,College of Chemistry and Chemical Engineering, Heilongjiang University, Harbin 150080;Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800,Institute of Functional Materials, Fuzhou University, Fuzhou 350002 and Institute of Functional Materials, Fuzhou University, Fuzhou 350002 |
| Abstract: | Three kinds of axially substituted silicon naphthalocyanine compounds (NcSiR2, R=Cl, OH, OCH3) have been synthesized. Excitation properties of the compounds have been investigated. The results indicate that the life for excitation singlet and triplet states, and generation of singlet-state oxygen are reduced with increase of push electronic properties of axially substituted groups. |
| Keywords: | silicon naphthalocyanine life of excitation single-state and tri-state single-state oxygen |
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