| SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES |
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| 引用本文： | 赵卫国,沈永嘉,李永舫,杨静. SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES[J]. 高分子科学, 1998, 0(3): 214-218 |
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| 作者姓名： | 赵卫国 沈永嘉 李永舫 杨静 |
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| 作者单位： | Institute of Fine Chemicals，East China University of Science and Technology，Shanghai 200237，China，Institute of Fine Chemicals，East China University of Science and Technology，Shanghai 200237，China，Laboratory of Organic Solids，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，China，Laboratory of Organic Solids，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，China |
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| 基金项目： | This work is supported by the National Natural Science Foundation of China(No.29574156)and the Foundation of the Open Laboratory of Organic Solids,Chinese Academy of Sciences |
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| 摘 要： | A polymer containing bis(ethylenedithio)-tetrathiafulvalene moiety wassynthesized and its electrochemical properties were studied by cyclic voltammetry. Thecharge transfer complexes of the polymer with TCNQ and I_2 were obtained by chemicaloxidation in dichlorobenzene. All of them are semi-conductors. A film of the polymer wasobtained by casting. Its conductivity, after oxidation with iodine, is 2.24×10~(-6)S·cm~(-1)and its conducting state is stable in air.
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| 收稿时间： | 1997-04-11 |
SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES* |
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| ZHAO Weiguo,SHEN Yongjia,LI Yongfang,YANG Jing. SYNTHESIS AND PROPERTIES OF POLYMERIC BIS (ETHYLENEDITHIO)-TETRATHIAFULVALENES*[J]. Chinese Journal of Polymer Science, 1998, 0(3): 214-218 |
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| Authors: | ZHAO Weiguo SHEN Yongjia LI Yongfang YANG Jing |
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| Affiliation: | Institute of Fine Chemicals; East China University of Science and Technology; Shanghai 200237; China Laboratory of Organic Solids; Institute of Chemistry; Chinese Academy of Sciences; Beijing 100080; China |
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| Abstract: | A polymer containing bis(ethylenedithio)-tetrathiafulvalene moiety wassynthesized and its electrochemical properties were studied by cyclic voltammetry. Thecharge transfer complexes of the polymer with TCNQ and I_2 were obtained by chemicaloxidation in dichlorobenzene. All of them are semi-conductors. A film of the polymer wasobtained by casting. Its conductivity, after oxidation with iodine, is 2.24×10~(-6)S·cm~(-1)and its conducting state is stable in air. |
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| Keywords: | Tetrathiafulvalene Charge-transfer-complex Conducting polymer |
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