| 3-对甲氧基苯基-和3-对羟基苯基-1-氨基-3a,4,5,9b-四氢化-9b-羟基-3H-环戊烯并[a]萘-2-甲腈的合成和晶体结构 |
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| 引用本文： | 史达清,荣良策,王菊仙,庄启亚.3-对甲氧基苯基-和3-对羟基苯基-1-氨基-3a,4,5,9b-四氢化-9b-羟基-3H-环戊烯并[a]萘-2-甲腈的合成和晶体结构[J].有机化学,2005,25(12):1560-1564. |
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| 作者姓名： | 史达清 荣良策 王菊仙 庄启亚 |
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| 作者单位： | 徐州师范大学化学系,徐州,221116 |
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| 基金项目： | 江苏省高校自然科学基金 |
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| 摘 要： | 用低价钛试剂(TiCl4-Zn)与2-氰基-3-对甲氧基苯基-3-(1-四氢萘酮-2-基)丙腈反应合成了3-对甲氧基苯基-1-氨 基-3a,4,5,9b-四氢化-9b-羟基-3H-环戊烯并a]萘-2-甲腈和3-对羟基苯基-1-氨基-3a,4,5,9b-四氢化-9b-羟基-3H-环戊烯并a]萘-2-甲腈, 并用X射线衍射分析确定了这两个产物的结构.
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| 关 键 词： | 低价钛 环戊烯并[a]萘-2-甲腈 合成 晶体结构 |
| 收稿时间： | 01 5 2005 12:00AM |
| 修稿时间： | 06 22 2005 12:00AM |
Synthesis and Crystal Structure of 3-(4'-Methoxyphenyl)- and 3-(4'-Hydroxyphenyl)-1-amino-3a,4,5,9b-tetrahydro-9b-hy-droxy-3H-cyclopenta[a]naphthalene-2-carbonitrile |
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| SHI,Da-Qing,RONG,Liang-Ce,WANG,Ju-Xian,ZHUANG,Qi-Ya.Synthesis and Crystal Structure of 3-(4''-Methoxyphenyl)- and 3-(4''-Hydroxyphenyl)-1-amino-3a,4,5,9b-tetrahydro-9b-hy-droxy-3H-cyclopenta[a]naphthalene-2-carbonitrile[J].Chinese Journal of Organic Chemistry,2005,25(12):1560-1564. |
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| Authors: | SHI Da-Qing RONG Liang-Ce WANG Ju-Xian ZHUANG Qi-Ya |
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| Institution: | Department of Chemistry, Xuzhou Normal University, Xuzhou 221116 |
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| Abstract: | 3-(4'-Methoxyphenyl)- and 3-(4'-hydroxyphenyl)-1-amino-3a,4,5,9b-tetrahydro-9b-hydroxy-3H- cyclopentaa]naphthalene-2-carbonitriles were synthesized by the reaction of low-valent titanium reagent (TiCl4-Zn) with 2-cyano-3-(4'-methoxyphenyl)-3-(1-tetralon-2-yl)propionitrile. Their structures were deter- mined by X-ray analysis. |
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| Keywords: | low-valent titanium reagent cyclopenta[a]naphthalene-2-carbonitrile synthesis crystal struc- ture |
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