Crossed beam studies of radical-radical reactions: O(3P) + C3H5 (allyl) |
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Authors: | Leonori F Balucani N Capozza G Segoloni E Stranges D Casavecchia P |
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Institution: | Dipartimento di Chimica, Università di Perugia, Perugia, Italy. |
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Abstract: | The dynamics of the radical-radical reaction O((3)P) + C(3)H(5) has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol(-1); the reaction mechanism of the H-displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C-C bond-breaking channels at this collision energy has been obtained. |
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