| 4-乙烯基吡啶与丙烯酰胺共聚合的研究 |
| |
| 引用本文： | 酒红芳,高保娇,曹霞.4-乙烯基吡啶与丙烯酰胺共聚合的研究[J].高分子学报,2002(4):438-442. |
| |
| 作者姓名： | 酒红芳 高保娇 曹霞 |
| |
| 作者单位： | 1. 华北工学院化学工程系,太原,030051
2. 太原市环境科学研究设计院,太原,030002 |
| |
| 基金项目： | 山西省青年科技基金资助项目 (基金号 940 13 ) |
| |
| 摘 要： | 以过硫酸钾为引发剂 ,采用溶液自由基共聚合方法 ,实现了丙烯酰胺 (AM)与 4 乙烯基吡啶 (4 VP)的共聚合 .通过详细研究共溶剂体系、单体总浓度、反应温度、反应时间及引发剂量对共聚合过程中转化率和分子量的影响 ,从而确定了适宜的共溶剂体系和最佳的工艺条件 .用紫外分光光度法测得了共聚物的组成 .用Kelen Tudos方法 ,求得 4 乙烯基吡啶 (4 VP)和丙烯酰胺 (AM)单体的竞聚率 ,r4 VP =0 6 4 4 ,rAM =0 371.最后通过FTIR和1 3C NMR表征共聚物的结构并验证了共聚物的组成 .
|
| 关 键 词： | 丙烯酰胺 4-乙烯基吡啶 溶液共聚合 竞聚率 |
| 修稿时间： | 2001年7月24日 |
THE STUDY ON THE COPOLYMERIZATION OF 4-VINYLPYRIDING AND ACRYLAMIDE |
| |
| JIU Hongfang,GAO Baojiao.THE STUDY ON THE COPOLYMERIZATION OF 4-VINYLPYRIDING AND ACRYLAMIDE[J].Acta Polymerica Sinica,2002(4):438-442. |
| |
| Authors: | JIU Hongfang GAO Baojiao |
| |
| Abstract: | The copolymerization of 4\|vinyl pyridine(4\|VP) with acrylamide(AM) has been realized by radical copolymerixation in solution using potassium persulfate as initiator.The effects of acetone/water and DMF/water solvent systems,comonomer concentration,polymerization temperature,polymerization time and initiator amount on the conversion of the polymerization and molecular weight were investigated in detail.The results showed that the mixed solvent DMF/water=1( V/V) is suitable for the copolymerization of 4\|VP and AM.The composition of copolymer was determined by ultraviolet spectrophotometry and the structure of copolymer was characterized and verified by FTIR and 13 C\|NMR.Finally,The monomer reactivity ratios of 4\|VP and AM were obtained with Kelen\|Tudos method, r \- 4\|VP =0\^644, r AM =0 371. |
| |
| Keywords: | Acrylamide 4\|Vinyl pyridine Solution copolymerization Reactivity ratio |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
