Biphilic properties of substituted triphenylphosphoranylideneacetonitriles bearing 4,5-Di(arylsulfonyl)-1,3-thiazol-2-yl fragments at the ylide center |
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Authors: | K V Turov E B Rusanov B S Drach |
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Institution: | (1) CNRS, LCC (Laboratoire de chimie de coordination), 205, voute de Narbonne, F-31077 Toulouse, France |
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Abstract: | Phosphonium ylides stabilized by nitrile and 4,5-di(arylsulfonyl)-1,3-thiazol-2-yl fragments show biphilic reactivity. They
react with aromatic aldehydes upon heating revealing a noticeable activity of ylide center and are condensed with typical
nucleophiles at C4 center of the thiazole ring with the elimination of arylsulfonyl group under mild conditions. New 1,3-thiazole derivatives
were obtained whose structures were proved by chemical, spectal and X-ray structural investigations. |
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Keywords: | |
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