Metal—ligand and π singlet—triplet transitions in phthalocyanine films studied by inelastic electron tunneling spectroscopy期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Metal—ligand and π singlet—triplet transitions in phthalocyanine films studied by inelastic electron tunneling spectroscopy

Authors:	U Roll S Ewert H Lüth

Institution:	2. Physikalisches Institut der Rheinisch-Westfalischen Technischen Hochschule Aachen, 5100 Aachen, Federal Republic of Germany

Abstract:	Inelastic electron tunneling spectroscopy (IETS) on AlAl₂O₃/PcPb tunneling junctions at 4.2 K has been used to study electronic transitions involving π, π^≠ and metal-ligand orbitals of phthalocyanine (Pc) films (H₂Pc, FePc, CoPc, NiPc, CuPc, ZnPc). The results are compared with calculations for Pc molecules.

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