Vibronic coupling activity in benzene |
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Authors: | Gad Fischer |
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Institution: | Department of Chemistry, Ben Gurion University of the Negev, Beer-Sheva, Israel |
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Abstract: | The absorption spectra of benzene-h6, -d3 and -d6 have been remeasured in the region of the hot band transitions 101601 and 801. Whereas for the first an intense doublet is found, for the latter two only a single intense peak is observed. This is taken as evidence of the inactivity of ν″8 in inducing intensity in contradiction to some recent calculations. The strong doublet for benzene-h6 has been attributed to Fermi resonance. |
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