Carbon-13 isotope enrichment in the photolysis of CO with the 123.58 nm Kr resonance radiation |
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Authors: | AC Vikis |
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Institution: | Division of Chemistry, National Research Council of Canada, Ottawa, Canada K1A 0R6 |
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Abstract: | The 123.58 nm Kr resonance radiation was shown to excite selectively the 13CO(A 1Π-X1Σ+) 13,0 transition in natural isotopic composition CO. The photolysis products, CO2 andC3O2, were enriched in carbon-13. Carbon dioxide was enriched ten-fold and the central carbon of C3O2 was enriched sixty-fold. |
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