Matrix elements for internal conversion |
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| Authors: | Willem Siebrand Marek Z Zgierski |
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| Institution: | Division of Chemistry, National Research Council of Canada, Ottawa, Canada K1A 0R6 |
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| Abstract: | The usual separation of internal conversion matrix elements into a momentum integral of the promoting modes and an overlap integral of the accepting mode is shown to introduce large errors. The proper procedure leads to the replacement of Franck-Condon factors by integrals involving the square root of an energy operator. |
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