N-n-butyl-N,N-di(2-naphthylmethyl)amine: A compound exhibiting intramolecular excimer and exciplex formation |
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| Authors: | G.S. Beddard R.S. Davidson T.D. Whelan |
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| Affiliation: | Davy Faraday Research Laboratory of the Royal Institution, London W1X 4BS, UK;Department of Chemistry, The University, Leicester LE1 7RH, UK |
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| Abstract: | The dinaphthylamine (3) is unique in that it exhibits both intramolecular excimer and exciplex formation. The relative amounts of each is dependent upon the solvent polarity. Highly polar solvents, e.g. methanol, lead to the emission being entirely that of the exciplex but addition of acid to these solutions prevents exciplex formation and only excimer is observed. |
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