The 19F shielding anisotropy of p-nitrofluorobenzene from nematic phase NMR |
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Authors: | J. Van Der Giessen C.A. De Lange |
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Affiliation: | Chemical Laboratory of the Free University, Amsterdam, The Netherlands |
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Abstract: | NMR experiments on p-nitrofluorobenzene dissolved in a nematic solvent are reported. It is shown that the 19F chemical shift tensor does not possess axial symmetry around the CF bond. For σaa ? σbb a value of 81 ppm, for σcc ? σbb a value of 156 ppm is determined. |
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