Erratum: Thermodynamic perturbation theory of a dense fluid of polar and polarizable spheres |
| |
| Authors: | G.N. Patey J.P. Valleau |
| |
| Affiliation: | Division of Chemistry, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6;Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A1 |
| |
| Abstract: | A method is described for determination of the dissociation energy D0 for hydrogen bonded dimers B…H-A using only measurements of rotational transition intensities at a single temperature. Application in the particular case HCN…HF gives D0 = 18.5 ± 1.1 kJ mol?1. By taking account of the vibrational modes of HCN…HF in the harmonic oscillator approximation, De is estimated as 25.6 ± 1.6 kJ mol?1. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
