Erratum: Thermodynamic perturbation theory of a dense fluid of polar and polarizable spheres |
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| Authors: | GN Patey JP Valleau |
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| Institution: | Division of Chemistry, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6;Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A1 |
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| Abstract: | A method is described for determination of the dissociation energy D0 for hydrogen bonded dimers B…H-A using only measurements of rotational transition intensities at a single temperature. Application in the particular case HCN…HF gives D0 = 18.5 ± 1.1 kJ mol?1. By taking account of the vibrational modes of HCN…HF in the harmonic oscillator approximation, De is estimated as 25.6 ± 1.6 kJ mol?1. |
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