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Collisional deactivation of laser-excited Br*(2P12) atoms with halogen and interhalogen molecules
Authors:Hubert Hofmann  Stephen R Leone
Institution:Joint Institute for Laboratory Astrophysics, National Bureau of Standards and University of Colorado and Department of Chemistry, University of Colorado, Boulder, Colorado 80309, USA
Abstract:Deactivation rates of spin-orbit excited Br*(2P12) atoms by halogens I2, Br2, and Cl2 and interhalogens IBr, ICl and BrCl have been measured by laser-excited, time-resolved infrared emission techniques. The results are effectively explained in terms of a collision complex formation model.
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