Collisional deactivation of laser-excited Br*(2P) atoms with halogen and interhalogen molecules |
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Authors: | Hubert Hofmann Stephen R Leone |
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Institution: | Joint Institute for Laboratory Astrophysics, National Bureau of Standards and University of Colorado and Department of Chemistry, University of Colorado, Boulder, Colorado 80309, USA |
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Abstract: | Deactivation rates of spin-orbit excited Br*(2P) atoms by halogens I2, Br2, and Cl2 and interhalogens IBr, ICl and BrCl have been measured by laser-excited, time-resolved infrared emission techniques. The results are effectively explained in terms of a collision complex formation model. |
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