Electron transfer promoted regioselective ring-opening reaction of cyclopropyl silyl ethers |
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| Authors: | Hasegawa Eietsu Yamaguchi Naoto Muraoka Hiroyasu Tsuchida Hiroyuki |
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| Affiliation: | Department of Chemistry, Faculty of Science, Niigata University, Ikarashi-2 8050, Niigata 950-2181, Japan. ehase@chem.sc.niigata-u.ac.jp |
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| Abstract: | Oxidative ring-opening reactions of cyclopropyl silyl ethers incorporated into bicyclo[m.1.0]alkane framework were investigated. The results show that the regioselectivities for ring-opening of intermediate radical cations, formed by single electron transfer, are governed by the nature of the nucleophile as well as oxidizing species. |
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