Inclusion and dielectric properties of a vinylidene fluoride oligomer in coordination nanochannels |
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| Authors: | Yanai Nobuhiro Uemura Takashi Kosaka Wataru Matsuda Ryotaro Kodani Tetsuhiro Koh Meiten Kanemura Takashi Kitagawa Susumu |
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| Affiliation: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | The dynamics of oligo(vinylidene fluoride) (OVDF) confined in regular nanochannels of a porous coordination polymer (PCP) was studied by means of dielectric spectroscopy. The OVDF chains in the PCP nanopores showed two Arrhenius-type relaxation processes at lower temperatures than the relaxation temperature observed for the neat OVDF, showing the enhanced mobility of the confined OVDF. |
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