On the heavy atom on light atom relativistic effect in the NMR shielding constants of phosphine tellurides |
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| Authors: | Irina L. Rusakova Yuriy Yu. Rusakov |
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| Affiliation: | A.E. Favorsky Irkutsk Institute of Chemistry, SB RAS, Irkutsk, Russia |
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| Abstract: | The relativistic HALA effect has been shown to depend on the spatial deformation of the lone electron pairs of a heavy atom, as demonstrated for alkyl and alkene phosphine tellurides. It was found that HALA effect on phosphorous nuclear magnetic resonance shielding constant is strongly dependent on the spatial arrangements of light substituents on phosphorus, resulting in the deformation of the lone electron pairs of tellurium. |
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| Keywords: | 31P NMR HALA effect phosphorus shielding constant tellurium |
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