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Kinetic study of the reaction of nucleophilic cyclopropanation of C60 fullerene with halogenated maleopimarimide |
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| Authors: | Yulya N Biglova Rauilya N Malikova Svetlana F Petrova Sergey P Ivanov Ilshat M Sakhautdinov Akhat G Mustafin |
| Institution: | 1. Department of Chemistry, Bashkir State University, Ufa, Russian Federation;2. Ufa Institute of Chemistry, Russian Academy of Sciences, 450054, Ufa, Russian Federation;3. Department of Chemistry, Bashkir State University, Ufa, Russian Federation
Ufa Institute of Chemistry, Russian Academy of Sciences, 450054, Ufa, Russian Federation |
| Abstract: | The kinetics of nucleophilic fullerene cyclopropanation by halomethyl ketones with a diterpene fragment has been studied by the Bingel method, and the influence of the biologically active cyclopropanating agent on the process has been estimated. It has been revealed that favorable conditions for carrying out the reaction result in maximum monofunctionalized methanofullerenes formation with the maximum yield. |
| Keywords: | [60] fullerene Bingel [2 + 1]-cycloaddition kinetic elucidation methyl maleopimarate rosin |