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Thermodynamics from the differential geometry standpoint
Authors:V P Pavlov  V M Sergeev
Institution:(1) Steklov Mathematical Institute, RAS, Moscow, Russia;(2) Center for Studying Global Problems, Moscow State Institute of International Relations, Moscow, Russia
Abstract:We study the differential-geometric structure of the space of thermodynamic states in equilibrium thermodynamics. We demonstrate that this space is a foliation of codimension two and find variables in which the foliation fibers are flat. We show that we can introduce a symplectic structure on this space: the external derivative of the 1-form of the heat source, which has the form of the skew-symmetric product dT 蝃 dS in the found variables. The entropy S then plays the role of the Lagrange function (or Hamiltonian) in mechanics, completely determining the thermodynamic system. __________ Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 157, No. 1, pp. 141–148, October, 2008.
Keywords:symplectic structure  space of states  dynamical principle
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