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Palladium catalyzed thiono-thiolo allylic rearrangement of o-allyl phosphoro- and phosphonothionates |
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| Authors: | Yoshimi Yamada Kunio Mukai Hirosuke Yoshioka |
| Institution: | Pesticide Division, Institute for Biological Science Sumitomo Chemical Co. Ltd. Takarazuka, Hyogo 665, Japan Department of Synthetic Chemistry, Kyoto University Yoshida, Kyoto 606, Japan |
| Abstract: | A new thiono-thiolo allylic rearrangement of phosphoro- and phosphono-thionates with Pd(PPh3)4 catalyst is described, where a variety of thionates are converted to the corresponding thiolates in excellent yields. |
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