Donor properties of the nitrone function in copper(II) complexes of some 2-hydroxy-1-naphthylnitrones |
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Authors: | Shanmugaperumal Sivasubramanian Paramasivam Manisankar Mallayan Palaniandavar Natesan Arumugam |
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Affiliation: | (1) School of Chemistry, Madurai Kamaraj University, 625 021 Madurai, India |
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Abstract: | Summary Copper(II) complexes of the type CuL2, 2H2O and CuL2. Py where L=-(2-hydroxy-1-naphthyl)-N-R-nitrone (R= methyl, phenyl and variously substituted phenyls) have been isolated and characterised. They have normal magnetic moments. Their ligand field spectra indicate an octahedral geometry for the dihydrates and a five-coordinate environment for the pyridine adducts. Increased (C=N) and considerably decreased (N-O) frequencies in these complexes reveal the presence of - and -interactions of the ligand with copper through nitrone oxygen. The effect of pyridine adduct formation is to increase the Cu-O -interaction. |
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