| 丁烯异构化L-H机理复杂反应动力学 |
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| 引用本文： | 金韵,俞启全,郭海,张令军,高惠璇.丁烯异构化L-H机理复杂反应动力学[J].化学学报,1988,46(8):727-733. |
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| 作者姓名： | 金韵 俞启全 郭海 张令军 高惠璇 |
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| 作者单位： | 北京大学化学系;北京大学数学系 |
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| 摘 要： | 用玻璃外循环无梯度反应器研究了丁烯异构化L-H机理复杂反应动力学. 用正交设计法估计了动力学方程中的参数. 色谱法测定了丁烯吸附热, 并研究了异构化生成反-2-丁烯及顺-2-丁烯的动力学方程.
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| 关 键 词： | 铵化合物 多相催化 反应动力学 Ｘ射线衍射分析 吸附 色谱法 丁烯 丁烯 磷酸盐P 铋化合物 |
The complex kinetics of L-H mechanism of isomerization of butenes |
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| JIN YUN,YU QIQUAN,GUO HAI,ZHANG LINGJUN,GAO HUIXUAN.The complex kinetics of L-H mechanism of isomerization of butenes[J].Acta Chimica Sinica,1988,46(8):727-733. |
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| Authors: | JIN YUN YU QIQUAN GUO HAI ZHANG LINGJUN GAO HUIXUAN |
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| Abstract: | The complex kinetics of L-H mechanism of isomerization of butenes has been investigated in flow-recirculation glass reactor. The parameters of kinetic equations were estimated by the method of orthogonal design. Gas-solid chromatog. has been used to measure the heats of adsorption of butenes. The kinetic equations for the isomerization to form trans-2-butene and cis-2-butene were developed. |
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| Keywords: | AMMONIUM COMPOUND HETERGENOUS CATALYSIS REACTION KINETICS X-RAY DIFFRACTION ANALYSIS ADSORPTION CHROMATOGRAPHY BUTENE BUTENE PHOSPHATE P BISMUTH COMPOUNDS |
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