Vibrational Distributions of N2 (A3∑+u) in the nitrogen afterglow |
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Authors: | W. Brennen R.V. Gutowski E.C. Shane |
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Affiliation: | Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, Penssylvania 19174, USA |
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Abstract: | Absolute populations of the lowest six vibrational levels of N2 (A3∑+u) have been measured under various conditions in the Lewis-Rayleigh afterglow of nitrogen for the first time. These vibrational distributions are interpreted in terms of a simple kinetic model which permits the evaluation of rate constants for vibrational relaxation of the A-state levels by V-V energy transfer to ground state nitrogen molecules. |
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